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Posted on February 14, 2020 by  & 
External Company Press Release

Deeper Insights into Solar Cells' Anatomy

Scientists at the Centre for Solar Energy and Hydrogen Research Baden-Württemberg (ZSW) now have a far more powerful tool to better investigate solar cells - a new scanning electron micro-scope. In full operation since January 2020, this device has twice the resolution of its predecessor and the ability to image structures measuring just a few nanometers. Its focused ion beam cuts cross-sections of layers smoothly and precisely. Researchers aim to gain a better understanding of thin-film solar cells' structure and interfaces on a nanoscale. They also want to gain deeper insights into defects. This knowledge is crucial to the solar industry's efforts to assure quality and continue to boost solar cells' efficiency. More efficient solar cells can further shrink photovoltaic systems' small CO2 footprint and boost PV's contribution to mitigating climate change. For further information see the IDTechEx report on Energy Harvesting Microwatt to Megawatt 2019-2029.
A video at shows the advantages of the new scanning electron microscope with a focused ion beam - or FIB-SEM for short.
High-resolution scanning electron microscopes are excellent analytical instruments for developing thin-film solar cells based on copper, indium, gallium and selenium (CIGS). The same goes for other solar cells such as perovskites. These tools furnish information about layer growth and thickness, morphology and chemical composition. They scan with an electron beam and render the smallest surface structures in three-dimensional images. These pictures help researchers spot undesirable cavities and foreign particles in the materials.
Nanoscale views for more nuanced observations
The new FIB-SEM at the ZSW is able to detect image points less than a nanometer apart. Solar cells' structures are clearly visible down to a scale of ten nanometers, or 0.00001 millimeters. "The device opens up new possibilities for us in the investigation of thin-film solar cells," says Dr. Theresa Friedlmeier, group leader Analytics and Simulation at the ZSW Department of Photovoltaics: Materials Research. "We can now analyze the shape and size of particles and inclusions, and investigate micro-areas using energy dispersive X-ray spectroscopy."
The new device can serve to examine the very thin interface between the CIGS and the buffer layer of cadmium sulfide with far greater depth and precision. This interface has a major impact on solar cell efficiency.
Improved sample preparation with a focused ion beam
With its focused ion beam, the new scanning electron microscope en-ables researchers to prepare materials on a nanoscale. "For example, we can use it to prepare good cross-sections of CIGS solar cells on flexible substrates without damaging or separating the individual layers, which had been very difficult in the past," says a clearly delighted Friedlmeier. "It helps us to deepen our understanding of solar cells and develop improved processes with higher efficiencies and lower costs." The state of Baden-Württemberg funded this new acquisition with a €650,000 grant.
The researchers will also use the new equipment to prepare the sam-ples for further investigations. These include electron backscattering, transmission electron microscopy, atom probe tomography and energy dispersive X-ray analysis.
About ZSW
The Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg (Centre for Solar Energy and Hydrogen Research Baden-Württemberg, ZSW) is one of the leading institutes for applied research in the areas of photovoltaics, renewable fuels, battery technology, fuel cells and energy system analysis. There are currently around 260 scientists, engineers and technicians employed at ZSW's three locations in Stuttgart, Ulm and Widderstall. In addition, there are 90 research and student assistants.
Media contacts ZSW
Claudia Brusdeylins, Zentrum für Sonnenenergie- und
Wasserstoff-Forschung Baden-Württemberg (ZSW) / Centre for Solar
Energy and Hydrogen Research, Meitnerstr. 1,
70563 Stuttgart, Germany, Phone +49 711 7870-278,
Axel Vartmann, PR-Agency Solar Consulting GmbH,
Emmy-Noether-Str. 2, 79110 Freiburg, Germany
Phone: +49 761 380968-23,,
Source and top image: ZSW
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